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Make sure to accept our cookies in order to get the best experience out of this website. If you would like to read more about this check out the Privacy Policy page. Your search results for english books. Baukal Jr. The double bond rule states that chemical elements with a principal quantum number greater than 2 for their valence electrons period 3 elements and lower should not form multiple bonds e.

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Although such compounds are not intrinsically unstable, they instead tend to polymerize. This effect is manifested by the rapid polymerization that occurs upon condensation of disulfur , the heavy analogue of O 2. This rule was challenged and ultimately disproven starting from with the isolation of crystalline samples of compounds with silicon—silicon and phosphorus—phosphorus double bonds. Another unrelated double bond rule exists that relates to the enhanced reactivity of sigma bonds once removed from a double bond.

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In bromoalkenes the C—Br bond is very stable but in an allyl bromide this bond is very reactive. Likewise bromobenzenes are generally inert whereas benzylic bromides are reactive. The first to observe the phenomenon was Conrad Laar in The name for the rule was coined by Otto Schmidt — in [10] [11]. From Wikipedia, the free encyclopedia. Glueck, R.

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